Tert butanol sodium CAS:865-48-5
Tert butanol sodium CAS:865-48-5
Tert butanol sodium, also known as sodium tert butoxide, is a white crystalline substance widely used as a strong base in chemical, pharmaceutical, pesticide, and organic synthesis reactions such as condensation, rearrangement, and ring opening.
sodiumt-butoxide,stb;sodiumt-butoxide,stb,in;Sodiumtert-butoxide,98%,pure;Sodiumtert-butoxide,99%;sodiuM2Chemicalbook-Methyl-1-oxopropan-2-yl;SodiuMtert-butoxide,pure,98%5GR;SODIUMTERT-BUTYLATEFORSYNTHESIS;SodiuMtert-butoxi
Tert butanol sodium Physical Properties:
Chemical Formula:
| Chemical | PAC-1 | PAC-2 | PAC-3 |
|
|---|---|---|---|---|
| Butyl alcohol, tert; (tert-Butanol) (75-65-0) | 150 ppm | 1300 ppm |
8000 ppm 
|
LEL = 24000 ppm |
Tert butanol sodium Alternate Chemical Names:
Tert butanol sodium Hazards:
Reactivity Alerts
Highly Flammable
Air & Water Reactions
Highly flammable. Water soluble.
Fire Hazard
This chemical is flammable. (NTP, 1992)
Health Hazard
Vapor is narcotic in action and irritating to respiratory passages. Liquid is irritating to skin and eyes. (USCG, 1999)
Reactivity Profile
Attacks plastics. [Handling Chemicals Safely 1980. p. 236]. Acetyl bromide reacts violently with alcohols or water [Merck 11th ed. 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: an explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73 1967; J, Org. Chem. 28:1893 1963]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous-carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969].
Belongs to the Following Reactive Group(s)
Alcohols and Polyols
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been known to react with the absorbent listed below. More info about absorbents, including situations to watch out for...
Cellulose-Based Absorbents
Tert butanol sodium Response Recommendations:
Isolation and Evacuation
Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Firefighting
Fire Extinguishing Agents Not to Be Used: Water may be ineffective on fire
Fire Extinguishing Agents: Dry chemical, carbon dioxide, or alcohol foam. (USCG, 1999)
Non-Fire Response
SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
STORAGE PRECAUTIONS: You should store this chemical in an explosion-proof refrigerator and keep it away from oxidizing materials. STORE AWAY FROM SOURCES OF IGNITION. (NTP, 1992)
Protective Clothing
Excerpt from NIOSH Pocket Guide for tert-Butyl alcoholexternal link:
Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.
Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.
Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.
Remove: WHEN WET (FLAMMABLE) - Work clothing that becomes wet should be immediately removed due to its flammability hazard (i.e., for liquids with a flash point <100��F).
Change: No recommendation is made specifying the need for the worker to change clothing after the workshift. (NIOSH, 2024)
DuPont Tychem? Suit Fabrics
Fabric legend, testing details, and a caution from DuPont
Normalized Breakthrough Times (in Minutes) Chemical CAS Number State QS QC SL C3 TF TP RC TK RF
Butanol, tert- 75-65-0 Liquid 37*/205 37*/205
Methyl propan-2-ol, 2- 75-65-0 Liquid 37*/205 37*/205
* indicates based on lowest single value.
Special Warning from DuPont: Tychem? and Tyvek? fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...
More Info...
(DuPont, 2024)
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Physical Properties
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